研究成果-化工学院刘涛老师课题组

研究成果

2024 2023 2022 2021 2020 2019 2018 2017 before 2016

2024

Hysteretic magnetism–dielectricity switching in 2D Hofmann type spin-crossover compounds

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Understanding of cooperative effects in molecule-based spin transition materials

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Substituent effect on the spin transition of Mixed-Valence Cyanide-Bridged {FeIII 2 FeII} complexes

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Tuning lanthanide luminescence from bipyridine-bis(oxazoline/thiazoline) tetradentate ligands

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Reversible light-induced spin state switching in a dinuclear Fe(II) spin crossover complex

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Constructing Alkyl Chain Modified FeII Spin Crossover Complexes through Complementary Pair Strategy

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Effects of mono- or di-fluoro-substitution on spin crossover behavior in a pair of Schiff base-like FeII-coordination polymers

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2023

Manipulating Metal-to-Metal Electron Transfer in Cyano-Bridged [Fe2Co]-Assembled Coordination Polymers

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Simultaneous magneto-dielectric transitions in a fluorescent Hofmann-type coordination polymer

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Design of Heterometallic {LnIII–MV} (Ln = Dy, Er; M = W, Mo) Molecular Nanomagnets: Protonation Induced Structural Diversification

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Manipulating fluorescence by photo-switched spin-state conversions in an iron(II)-based SCO MOF

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Colossal Anisotropic Thermal Expansion through Coupling Spin Crossover and Rhombus Deformation in a Hexanuclear {FeIII 4FeII 2} Compound

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Ligand Modified and Light Switched On/Off Single-Chain Magnets of {Fe2Co} Coordination Polymers via Metal-to-Metal Charge Transfer

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A cyanide-bridged FeII–MoV-based coordination polymer showing spin crossover

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A Smart Molecule Showing Spin Crossover Responsive Aggregation-Induced Emission.

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Enhanced magnetic anisotropy and Single-chain magnet behavior via Photo-induced charge transfer

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Dinuclear and trinuclear cyano-bridged {DyIIIMIV} (M = W, Mo) single-ion magnets supported by pentadentate Schiff-base ligands

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Construction of spin crossover-fluorescence bifunctional iron(ii) complexes with modified bis(pyrazole)pyridine ligands

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Regulating Magnetic Relaxations of Cyano-Bridged {DyIIIMoV } Systems by Tuning the N-Sites in β-Diketone Ligands

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Magnetoelectric effect generated through electron transfer from organic radical to metal ion

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Constructing spin crossover-fluorescence bifunctional iron(II) complexes based on tetraphenyl ethylene-decorated AIEgens

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Structures and magnetic relaxation properties of cyclopentadienyl/β-diketonate/trispyrazolylborate hybridized dysprosium single-molecule magnets

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2022

Simultaneous Photo-Induced Magnetic and Dielectric Switching in an Iron(II)-Based Spin-Crossover Hofmann-Type Metal-Organic Framework

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Spin-Crossover Tuned Rotation of Pyrazolyl Rings in a 2D Iron(II) Complex towards Synergetic Magnetic and Dielectric Transitions

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Construction of spin-crossover dinuclear cobalt(II) compounds based on complementary terpyridine ligand pairing

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Slow magnetic relaxation in mononuclear octa-coordinate Fe(II) and Co(II) complexes from a Bpybox ligand

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Achieving large thermal hysteresis in an anthracene-based manganese(II) complex via photo-induced electron transfer

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The substituent effect on the spin-crossover behaviour in a series of mononuclear Fe(II) complexes from thio-pybox ligands

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Ligand Modified and Light Switched On/Off Single-Chain Magnets of {Fe2Co} Coordination Polymers via Metal-to-Metal Charge Transfer

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2021

Thermal and photoinduced spin-crossover of mononuclear FeII complexes based on bppCHO ligand

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Construction of Magneto-Fluorescent Bifunctional Spin Crossover Fe(II) Complex from Pyrene-Decorated Pybox Ligand

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Ferromagnetic Archimedean polyhedra {Fe24M18} (M = Fe, Ni, and Mn) with tunable electron configurations

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Switching the magnetic hysteresis of an [Feii–NC–Wv ]-based coordination polymer by photoinduced reversible spin crossover

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Asymmetric Coordination Toward a Photoinduced Single-Chain Magnet Showing High Coercivity Values

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Ligand symmetry significantly affects spin crossover behaviour in isomeric [Fe(pybox)2] 2+ complexes

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2020

A Mixed-Valence {Fe13} Cluster Exhibiting Metal-to-Metal Charge Transfer-Switched Spin Crossover

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Construction of SCO-Active Fe(II) Mononuclear Complexes from the Thio-pybox Ligand

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Experimental Determination of Magnetic Anisotropy in Exchange Bias Dysprosium Metallocene Single-Molecule Magnets

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2019

Weak exchange coupling effects leading to fast magnetic relaxations in a trinuclear dysprosium single-molecule magnet

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Effect of Intermolecular Interactions on Metal-to-Metal Charge Transfer: A Combined Experimental and Theoretical Investigation

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Photo-switched magnetic coupling in spin-crossover complexes

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Design principle of half-sandwich type erbium single-ion magnets through crystal field engineering: a combined magnetic and electronic structure study

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Synergistic catalysis for light-driven proton reduction using a polyoxometalate-based Cu–Ni heterometallic–organic framework

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Manipulating Spin Transition To Achieve Switchable Multifunctions

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Spin crossover and structural phase transition in homochiral and heterochiral Fe[(pybox)2] 2+ complexes

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Single-Molecule Magnet Behavior in Two Tetranuclear Cyanide bridged FeIII 2NiII 2 Compounds

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Magnetic investigations over reversibly switched chiral (phthalocyaninato)(porphyrinato) dysprosium double-decker compounds

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2018

Manipulating Metal-to-Metal Charge Transfer for Materials with Switchable Functionality

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Controlling magnetic exchange coupling via coligands in three cyanide bridged heterobimetallic complexes

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Manipulation of successive crystalline transformations to control electron transfer and switchable functions

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Controlling assembly and single-molecule magnet behavior of Fe-Ni clusters utilizing steric effect

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Simultaneous Modulation of Magnetic and Dielectric Transition via Spin-Crossover-Tuned Spin Arrangement and Charge Distribution

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Fluorescence modulation via photoinduced spin crossover switched energy transfer from fluorophores to FeII ions

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Dual-Excitation Polyoxometalate-Based Frameworks for One-Pot Light-Driven Hydrogen Evolution and Oxidative Dehydrogenation

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Low-Coordinate Single-Ion Magnets by Intercalation of Lanthanides into a Phenol Matrix

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Fluorescence modulation via photoinduced spin crossover switched energy transfer from fluorophores to FeII ions

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Switching single chain magnet behavior via photoinduced bidirectional metal-to-metal charge transfer

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2017

A Series of Linear {FeIII2FeII} Complexes with Paramagnetic Building-Block-Modified Spin Crossover Behaviors

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A Material Showing Colossal Positive and Negative Volumetric Thermal Expansion with Hysteretic Magnetic Transition

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Synergic on/off Photoswitching Spin State and Magnetic Coupling between Spin Crossover Centers

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Two-Step Spin-Crossover with Three Inequivalent FeII Sites in a Two-Dimensional Hofmann-Type Coordination Polymer

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Three Properties in One Coordination Complex: Chirality, Spin Crossover, and Dielectric Switching, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

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Light-Induced Bidirectional Metal-to-Metal Charge Transfer in a Linear Fe2Co Complex, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

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Photo- and Electronically Switchable Spin-Crossover Iron(II) Metal-Organic Frameworks Based on a Tetrathiafulvalene Ligand

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119Sn Mossbauer and Ferromagnetic Studies on Hierarchical Tin- and Nitrogen-Codoped TiO2 Microspheres with Efficient Photocatalytic Performance

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Alkyne Activation by a Porous Silver Coordination Polymer for Heterogeneous Catalysis of Carbon Dioxide Cycloaddition

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Controllable antiferromagnetic to ferromagnetic coupling in polynuclear Fe(III)-Co(II) heterobimetallic complexes

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before 2016

Rational enhancement of the energy barrier of bis(tetrapyrrole) dysprosium SMMs via replacing atom of porphyrin core

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12-Metal 36-membered ring based WV-CoII layers showing spin-glass behavior

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Charge Transfer Induced Multifunctional Transitions with Sensitive PressureManipulation in a Metal-Organic Framework

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Two cyano-bridged {FeIII4MII2}c(M=FeII, CoII) hexanuclear complexes with dominant ferromagnetic interactions

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Two octacyanometallate based WVNiII and MoVNiII chains with dominant ferromagnetic interactions

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Single-molecule magnet behavior in three cyano-bridged heterometallic FeIII-NiIIclusters

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A cyano-bridged tubular coordination polymer with dominant ferromagnetic interactions

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A ferromagnetically coupled Fe42 cyanide-bridged nanocage

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Structural phase transition in a multi-induced mononuclear FeII spin-crossover complex

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Two octacyanometallate based (WVNiII) and (MoVNiII) chains with dominant ferromagnetic interactions

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Cyano-bridged Fe2Cu double-zigzag chains: From metamagnetism to coexistenceof metamagnetism and single-chain magnet behavior

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Cyano-bridged Fe2Cu double-zigzag chains: From metamagnetism to coexistenceof metamagnetism and single-chain magnet behavior

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Cyano-bridged Fe2Cu double-zigzag chains: From metamagnetism to coexistenceof metamagnetism and single-chain magnet behavior

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From tetranuclear cluster with single-molecule-magnet behavior to 1D alternating spin-canting chain in a Fe(III)-Mn(III) bimetallic system

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From tetranuclear cluster with single-molecule-magnet behavior to 1D alternating spin-canting chain in a Fe(III)-Mn(III) bimetallic system

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Enhanced Spin-Crossover Behavior Mediated by Supramolecular Cooperative Interactions

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Enhanced Spin-Crossover Behavior Mediated by Supramolecular Cooperative Interactions

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Selective on/off switching at room temperature of a magnetic bistable {Fe2Co2}complex with single crystal-to-single crystal transformation via intramolecular electron transfer

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Selective on/off switching at room temperature of a magnetic bistable {Fe2Co2}complex with single crystal-to-single crystal transformation via intramolecular electron transfer

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Cyanide bridged Fe2Cu clusters: control of magnetic properties through cis-trans arrangement, inorganic chemistry communications

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Cyanide bridged Fe2Cu clusters: control of magnetic properties through cis-trans arrangement, inorganic chemistry communications

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Naphthyridine-based lanthanide complexes worked as magnetic resonance imaging contrast for guanosine 5 '-monophosphate in vivo

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Naphthyridine-based lanthanide complexes worked as magnetic resonance imaging contrast for guanosine 5 '-monophosphate in vivo

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Mixed (phthalocyaninato)(Schiff-base) di-dysprosium sandwich complexes. Effectof magnetic coupling on the SMM behavior

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Mixed (phthalocyaninato)(Schiff-base) di-dysprosium sandwich complexes. Effectof magnetic coupling on the SMM behavior

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Field-induced slow relaxation of magnetization in a tetrahedral Co(II) complex with easy plane anisotropy

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Field-induced slow relaxation of magnetization in a tetrahedral Co(II) complex with easy plane anisotropy

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A near-infrared dye based on BODIPY for tracking morphology changes inmitochondria

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A near-infrared dye based on BODIPY for tracking morphology changes inmitochondria

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A light-induced spin crossover actuated single-chain magnet

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A light-induced spin crossover actuated single-chain magnet

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Binuclear Phthalocyanine-Based Sandwich-Type Rare Earth Complexes: Unprecedented Two -Bridged Biradical-Metal Integrated SMMs

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Slow magnetic relaxation in a cyano-bridged ferromagnetic {FeIIINiII}-Ni-III} alternating chain

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Synthesis, Structure, and Single-Molecule Magnetic Properties of Rare-EarthSandwich Complexes with Mixed Phthalocyanine and Schiff Base Ligands

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Mixed (phthalocyaninato)(Schiff-base) di-dysprosium sandwich complex. Effect of magnetic coupling on the SMM behavior

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A Photoactive Basket-like Metal-organic Tetragon Worked as an Enzymatic Molecular Flask for Light Driven H2 Production

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Naphthyridine based lanthanide complexes worked as magnetic resonance imaging contrast for guanosine 5-monophosphate in vivo

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Above-Room-Temperature Magnetodielectric Coupling in a Possible Molecule-Based Multiferroic: Triethylmethylammonium Tetrabromoferrate(III)

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Mild hydrothermal synthesis, structure and characterization of the vanadyl phosphate hydrate Pb(VOPO4)23H2O: the formation of spin dimers in a three dimensional crystal structure

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Synthesis, structures and single chain magnet behavior of a cyano-bridged {Fe2Cu} chain

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A hexanuclear gadolinium-organic octahedron as a sensitive MRI contrast agent for selectively imaging glucosamine in aqueous media

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Single-molecule magnet behavior in a tetranuclear cyano-bridged FeIII2NiII2 cluster

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Magnetic fluorescent bifunctional spin-crossover complexes

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Coexistence of metamagnetism and single chain magnet behavior in a FeIII2CoII layer compound

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Structural and Magnetic Properties of 57Fe-Doped TiO2 and 57Fe/Sn-Codoped TiO2 Prepared by a Soft-Chemical Process

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Coexistence of the single chain magnet and spin-glass behavior in a cyano-bridged {FeIII2FeII} chain

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Organized Aggregation Makes Insoluble Perylene Diimide Efficient for the Reduction of Aryl Halides via Consecutive Visible Light-Induced Electron-Transfer Processes

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Syntheses, structures, and magnetic properties of three new cyano-bridged heterobimetallic chains based on [Fe(Tp*)(CN)3]-

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Spin transitions in a series of [Fe(pybox)2]2+ complexes modulated by ligand structures, counter anions, and solvents

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Construction of solvent-dependent self-assembled porous Ni(II)-coordinated frameworks as effective catalysts for chemical transformation of CO2

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